544
[621
621.
ON THE NUMBER OF THE UNIVALENT RADICALS C„H W .
[From the Philosophical Magazine, series 5, vol. m. (1877), pp. 34, 35.]
I have just remarked that the determination is contained in my paper “On the
Analytical Forms called Trees, &c.,” British Association Report, 1875, [610]; in fact, in
the form C n H 2n -H, there is one carbon atom distinguished from the others by its being
combined with (instead of 4, only) 3 other atoms; viz. these are 3 carbon atoms, 2
carbon atoms and 1 hydrogen atom, or else 1 carbon atom and 2 hydrogen atoms
(CH., methyl, is an exception; but here the number is =1). The number of carbon
atoms thus combined with the first-mentioned atom is the number of main branches,
which is thus = 3, 2, or 1; hence we have, number of radicals C il H 2n+1 is =
No. of carbon root-trees C n with one main branch,
+ No. of „ „ with two main branches,
+ No. of „ „ with three main branches;
and the three terms for the values n = 1 to 13 are given in Table VII. (pp. 454, 455
of this volume) of the paper referred to.
Thus, if n = 5, an extract from the Table (p. 454 of this volume), is
Index x, or
number of
knots
Index t, or num
ber of main
branches
Altitude
0
1
2
3
4
5
1
1
2
1
4
2
2
1
3
3
1
1
4
1
1
Total ...
1
4
3
1
9