100
THE QUANTUM [vn. 4
“ Our ordinary electrodynamic conceptions are probably
insufficient to form a basis for an explanation of atomic
magnetism. This is hardly to be wondered at when we
remember that they have not proved adequate to account for
the phenomena of radiation which are connected with the
intimate interaction between the electric and magnetic forces
arising from the motion of the electrons. In whatever way
these difficulties may be solved it seems simplest to assume that
the occurrence of magnetism, such as we meet in the elements
of the fourth period, results from a lack of symmetry in the
internal structure of the atom, thus preventing the magnetic
forces arising from the motion of the electrons from forming a
system of closed lines of force running wholly within the atom.
While it has been assumed that the ions of the elements in the
previous periods, whether positively or negatively charged, con
tain configurations of marked symmetrical character, we must,
however, be prepared to encounter a definite lack of symmetry
in the electronic configurations in ions of those elements within
the fourth period which contain a group of electrons in 3-quanta
orbits in the transition stage between symmetrical configurations
of 8 and 18 electrons respectively. As pointed out by Kossel,
the experimental results exhibit an extreme simplicity, the
magnetic moment of the ions depending only on the number of
electrons in the ion. Ferric ions, for example, exhibit the same
atomic magnetism as manganous ions, while manganic ions exhibit
the same atomic magnetism as chromous ions. It is in beautiful
agreement with what we have assumed about the structure of the
atoms of copper and zinc, that the magnetism disappears with
these ions containing 28 electrons which, as I stated, must be
assumed to contain a complete group of 3-quanta orbits. On
the whole a consideration of the magnetic properties of the
elements within the fourth period gives us a vivid impression
of how a wound in the otherwise symmetrical inner structure
is first developed and then healed as we pass from element to
element. It is to be hoped that a further investigation of the
magnetic properties will give us a clue to the way in which the
group of electrons in 3-quanta orbits is developed step by step.”
If we assume with Bohr that paramagnetism is independent
of the nucleus of the atom but is governed entirely by the
electronic orbits, we should expect the magnetic effect to be the
same in all atoms with the same number of electrons even though
the nuclear charges differ. This expectation is in accordance
with the experimental results at present available. For example,
the ferric ion, Fe +++ , and the manganous ion, Mn ++ , both having
23 electrons, are similar in their magnetic properties.
A scheme for the distribution of electrons among atomic