80
THERMODYNAMIC METEOROLOGY
Example 7. Pressure of Vapor in Contact with Water and Ice
P12 = 4.57 vapor-water.
Vi = 205000.
Pis = 760 vapor-ice. v 2 = 1.00
P 2 3 = . water-ice. v 3 = 1.09
T = 0.0074° C., the fundamental temperature.
(295) Vapor on water.
d P i2
~dT
r 12 41851000 760
T (»! - Vi) 1 1013235'
606.5 3.1391 X 10 4
273 ’ 204999
0.3402 mm.
(295)
Vapor on ice.
dPu
dT
go r n
A T (vi - v 3 )
(606.5 + 80) 3.1391 X 10 4
273 ’ 204999
0.3851 mm.
(296)
Water on ice.
d P23 _ go r 2 3
dT AT (v 2 — v 3 )
80.066 3.1391 X 10 4
273 ’ (-0.09)
102294. mm.
Compare Planck’s “Thermodynamik.”
Application of the Thermodynamic Formulas to the N on-Adiabatic
Atmosphere
The foregoing formulas would apply to an adiabatic atmos
phere, using the constants of Table 3, wherein Cp, Cv, R are
constants, but they do not apply to the existing non-adiabatic
atmosphere, because it is not an ideal gas, rather a mixture of
gases which are undergoing rapid changes of condition through
variations in the heat contents by insolation and radiation.
They can, however, be adapted to the earth’s atmosphere by
suitable modifications, which depend upon the formulas de
veloped under static meteorology. The following summary is
sufficient for working purposes.