For vegetative objects some theoretical model is needed which
correlates bidirectional reflectance of a plant canopy or field, as
measurable by airborne scanners, and the laboratory reflectance spectra
of the constituent plant components. For geological objects a model is
needed which will permit assessment and/or correlation for variations
in texture of rock surfaces across the scene as they affect discrimina-
tion among certain rock types. Suits [11] in an important development
has devised a canopy model of the type needed which allows for more than
one canopy layer and which relates laboratory spectra of plant components
and approximate plant geometry (Planting density and average horizontal
and vertical component cross sections) to the bidirectional reflectance
of a crop field which it predicts without atmospheric effects. The
model has been verified [12, 13] for the case of mature corn by field
reflectance measurements at different angles over the visible and near
infrared spectral bands.
The problems encountered in geological remote sensing are different
in several aspects from vegetative problems. First, temporal effects
are much slower for geological than for vegetative objects. Secondly,
for rock-type identification the spectral emittance or reflectance
variations are much more important than geometrical variations (shapes,
shadows, observation angle, etc.) across the scene, whereas both are
relatively important for the identification of vegetative classes.
Thirdly, the thermal IR spectral region contains more chemically
diagnostic information about rocks than the visible-reflective IR wave-
length regions, whereas the converse is true for vegetative classes.
Rocks and minerals present a special problem in the thermal IR
region not normally encountered in the shorter wavelength regions.
Thermal IR wavelengths (A & 10 um) approach in size the particle
diameters of some of the grains in fine-textured rock surfaces, which
produces some complex optical phenomena related to surface roughness.
For instance, it has been noted by Lyon [14] and other investigators
that the spectral emittance within the major reststrahlen bands
(intramolecular vibration modes in this case) of silicate rocks and
minerals tend to increase with decreasing particle size. Later work
[15] has shown that in spectral regions of moderate to small complex
refractive index, outside the reststrahlen bands (high complex refractive
index), the emittance can either increase or decrease with decreasing
particle size.
The spectral emittance dependence on particle size is an important
factor in geological remote sensing, because textural variations from
rock to rock may mask differences in chemical composition and vice
versa. It is necessary, therefore, to separate textural and chemical
effects on the spectral emittance, as much as possible. To do this, a
model of rough rock and mineral surfaces is required which can at least
qualitatively explain the effect of textural variations on the IR spectrum
of those surfaces. The resulting calculated spectral emittances are
specifically needed to assess what affects textural variations have on
discrimination techniques.
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