. that no diffusion from the grain interior appears and that the intercrystalline
sulphide sulphide is not caused by a sulphur diffusion from inside to the solidified grain
boundaries.
oundaries
250°C for It seems that the sulphur originates from the segregation at solidification, but
ied steel the results of the investigations have not been sufficient yet to draw a final
conclusion where intercrystalline sulphide really originates from during the
cooling process after solidification.
REFERENCES
1. K.Yasumoto, Y.Maehara, S.Ura and Y.Ohmori: Mater. Scie. Technol. 1985, 1, 111.
2. G.A.Osinkolu, M.Tacikowski and A.Kobylanski: Mater. Scie. Technol., 1985, 1, 520.
3. H. Fredrikson and J. Stjerndahl: Metall. Trans., 1977, 84, 1107.
solidifi 4, T.Williams, A.M.Stoneham and D.R.Harries: Met. Scie., 1976, 10, 14.
sr parti- 5. D.R.Harries and A.D.Marwick: "Residuals, Additives and Materials Properties",
colidifio 197; 1980, London, The Royal Society.
6. F. Vodopivec and M. Torkar: Mem. Etud. Sci. Rev. Metall., 1982, 79, 557.
7. F. Vodopivec: in Proc. of 5th Jugoslavian Symp. on "Electron microscopy", Zagreb,
May 1986, Croatian Society for National Sciences, 23-29.
8. D.R.Beaman and J.A.Isasi: in "Electron Beam Microanaly". STP 506 (ed.D.R.Beaman
and J.A.Isasi), 56; 1972, AMS.
9. J.I.Coldstein and J.W.Golby: in "Practical Scanning Electron Microscopy" (ed.
rticle J.I.Goldstein and H. Jakowiz) 443-456; 1977, New York, Plenum Press.
cooling 10. M. Fisher and K. Schwerdtfeger: Metall. Trans..., 1978, 9B, 631.
ntent of 11. L. Nedeljkovié: unpublished work (discussion contribution to Conf. on "Residuals
n steels in Iron and Steel", PortoroZ, YU, oct. 1985, IRSID/MPIE/MIL.
ced when
stalline
nn solid
~face of
sulphide
fication
tance of
confirms
Prakt. Met. Sonderbd. 22 (1991)
469