845
(X = 532 nm). The width of this band (at half-height) would correspondingly
vary from 10 to 18 nm in this case. This allows some optimalization of the
spectrum detected by changing the wavelength of excitation to avoid bands
overlapping in particular cases, as well as to provide appropriate spectral
position of WRS signal.
The in vivo chlorophyll fluorescence provides contribution at 685 nm
(Fig.2) with a half-height of about 20 nm. From this point the utilization of
the second harmonic of Nd:YAG laser at 532 nm may be considered as
near-optimal (Klyshko and Fadeev, 1978). When excited with a UV source, the
DOM fluorescence shows an extremely broad band, overlapping the whole visible
spectrum from UV to the far red area (e.g. see Reuter, 1993; Patsayeva, 1994)
and possessing a maximum emission at 440 nm. The spectra of oil products
(dissolved or being in film on water surface) can vary in a wide range,
depending on the kind of product and its "water history". More detailed
information on this, as well as concerning the problem of distinguishing
between oil and contribution to the spectrum one may find in (Patsayeva,
1994). We should just underline here, that the relative contributions of
different fluorescent bands to the total spectrum can vary in a very wide
range, particularly in coastal waters. It can lead to significant difficulties
in spectral processing and data interpretation, and should be taken into
account.
3 - LIDAR-FLUOROSENSOR INSTRUMENTATION
3.1. Lasers
The general requirements for a laser to be utilized in lidar-fluorosensor
system are pulsed operation, nanosecond pulse duration, high reliability,
convenience of operation in field condition, compact size and light weight,
low power consumption. In Table 1 one can find some general characteristics of
suitable lasers available. The right three columns reflect the relative
efficiency of lasers application to excite fluorescence of particular objects
(oil, dissolved organic matter (DOM), chlorophyll-a (Chl-a)), taking into
account the parameters listed and optical characteristics of water and
objects.
Table 1. General characteristics of lasers utilized in lidar-fluorosensors
Laser
type
Wa velength
nm
Pu lse
power,
mJ
Pulse
per
second
Oil
DOM
Chl-a
Excimer XeCl
308
100-200
50-200
***
* *
-
Nitrogen
337
0 . 1-1
10 2 -10 3
*
* *
Nd:YAG
355
10-50
5-10
*
* *
*
Dye
3 90-450
10-30
5-20
-
*
**
Nd:YAG
532
30-150
5-20
-
*
***
3.2. Detecting systems
The telescope of 20-30 cm aperture (Newton- or Cassegrain-type) is generally
used to collect an optical response from the water column caused by pulsed
laser excitation. Due to high variability in detection conditions (moving