The International Archives of the Photogrammetry, Remote Sensing and Spatial Information Sciences. Vol. XXXVII. Part B7. Beijing 2008
be found in Brereten (2000), Martens and Naes (1989), Wold et
al., (2001), Yeniay and Goktas (2002), http://www.camo.com.
3. RESULTS AND DISCUSSIONS
3.1 ENGINEERING AND SPECTRAL PARAMETERS
Values of engineering parameters indicate that the soil samples
have a wide range of variability in their expansion potential (e.g.
Figure 2 plasticity chart). Distribution of samples on plasticity
chart is useful in getting indication of soil expansion potential
(Dakshanamurty and Raman, 1973). Consistency or Atterberg
limits are ranges of consistency (the ease with which a soil can
be deformed) of cohesive soils as a function of changes in
moisture content (Perloff and Baron, 1976). They represent
empirical boundaries which divide various states that cohesive
soils exhibit with varying amount of moisture content; solid,
semisolid, plastic and semi-liquid states. Since water has a
significant effect on engineering behaviour of clayey soils in
such a way that clayey soils with higher moisture content are
weaker and easily deformable than their same varieties with
lower moisture content (Lambe and Whitman, 1979; Mitchell,
1993; Perloff and Baron, 1976), determination of consistency
limit values of such soils has proved to be useful in engineering
applications.
Figure 3. Distribution of soil samples on plasticity chart.
Differences in spectral characteristics among spectra of
different soil samples were used in differentiating various clay
mineral types present in the soil samples. Position of absorption
features, their shapes, types and number, depth intensity and
asymmetry; shape of spectral curves, differences in slopes of
spectral curves and variations in reflectance intensity of spectra
were some of the important qualitative parameters that helped
to identify spectrally dominant clay mineral from the soil
reflectance spectra. Up on spectral interpretation, spectra of soil
samples were grouped into three major classes of mineralogical
composition; smectites, mixtures and kaolinites (Figure 3).
Among smectite classes are montmorillonite and nontronite and
of kaolnite groups are halloysite and kaolinites. Those that are
grouped under mixtures are a mixture of smectites, kaolinites
and others.
Figure 4. Variability in spectral characteristics of different soil
samples (no offset). Note the differences in shapes of spectral
curves; overall reflectance intensity, shape, position and
number of absorption bands among the spectra.
Relationships between measured engineering parameters and
mineralogical classes obtained upon spectral interpretation with
respect to the magnitude of relationship each mineralogical
classes show with absorption feature parameters were examined
(Figure 4).
Figure 5. Scatter plots showing the relationship between depth
at -1900 nm and liquid limit of different clay mineral
categories; showing the magnitude of the linear relationship per
mineralogical groups (kaolinites, mixtures & smectites).
The magnitude of relationship between absorption feature depth
at ~ 1900 nm and liquid limit of samples is highest for smectites
that exhibit strong absorption band at ~ 1900 nm due to
adsorbed water in their structure, followed by mixtures.
Kaolinites that show no (kaolin) or less resolved (halloysite)
absorption at ~ 1900 nm show the lowest correlation between
liquid limit and depth of absorption feature at ~ 1900 nm.
3.2 PARTIAL LEAST SQUARES (PLSR) PREDICTION
MODELS
Absorption feature parameters (position, depth, area, width of
absorption feature) calculated from absorption bands at -1400
1321