132
THE QUANTUM [i X . 5
results given in the table. It may be pointed out that the method
would also lead to unsymmetrical configurations which would
yield different values for the characteristic constants.
It is of interest to note that from a study of the secondary
spectrum of hydrogen at higher pressures, Sandeman * has isolated
a band, showing a P, Q, and R combination having a moment
of inertia agreeing within the errors of measurement with that
found for this static model of triatomic hydrogen.
5. A Static Model for Helium
For the positively charged helium atom,f consisting of a
positively charged nucleus (charge + 2e) and a single negative
electron (charge — e), there is a position of stable equilibrium
determined by r — \a n . The work that must be done to remove
the electron from this position to a position of rest at an infinite
distance from the nucleus is four times the corresponding amount
in the case of the hydrogen atom, exactly as in Bohr’s original
theory. It is assumed that there is repulsion between nucleus
and electron due to the quantum force, of amount e 2 a n /r 3 .
For a neutral helium atom, consisting of a positive nucleus
and two electrons, a number of configurations are theoretically
possible. We consider first symmetrical configurations in which
the nucleus is at the middle point of the line joining the electrons.
The table below gives the results for two possible models, A and
B. A refers to a model in which no quantum force acts between
the electrons, and B to a model in which such a force is included.
Data for Helium Atom
r (A.U.)
W t (volts)
Ionized helium atom, C .
0-265
54-ïo
Neutral helium atom, A .
0-303
82-84
Neutral helium atom, B .
0-265
94-67
Change from A to C
—
2874
Change from B to C
—
4°'57
These values of W for the neutral atom are not in agreement
with the experimental results, which yield the value 78-6 volts.
If, however, we assume with Bohr that a neutral atom is formed
by the successive binding of electrons by the atomic nucleus, it
may be that the symmetrical arrangement assumed is never
* Sandeman, Proc. Roy. Soc., voi. 108, p. 607, 1925.
t H. S. Allen, Proc. Roy. Soc. Edin., voi. 44, p. 116, 1924.