CHAPTER XVII
THE NEW QUANTUM MECHANICS
It is to be hoped that a new era of mutual stimulation of mechanics
and mathematics has commenced. To the physicists it will at first
seem deplorable that in atomic problems we have apparently met
with such a limitation of our usual means of visualization. This
regret will, however, have to give way to thankfulness that mathe
matics, in this field too, presents us with the tools to prepare the
way for further progress.
Niels Bohr, Nature, December 5, 1925
1. The Work of Heisenberg
I N the nineteenth century classical electrodynamic theory had
considerable success in explaining many of the phenomena
of atomic physics, but other facts emerged which seemed to
necessitate a radical departure from this theory. During the first
quarter of the present century many attempts were made to
meet these difficulties by means of special assumptions and rules,
which constituted the quantum theory. Although these methods
have had remarkable success in the interpretation of a restricted
set of phenomena, it has long been felt that such a procedure,
designedly adopted with a particular end in view, was not satis
factory and that a more general theory was required.
In 1925 Heisenberg * put forward a new theory of quantum
mechanics which has had far-reaching consequences, and seems
to point the way to a complete solution of the problem from the
mathematical standpoint. One of the fundamental ideas
employed by Heisenberg is that only such things as are directly
open to observation should enter into the mathematical formula
tion. He considered it advantageous to avoid every concept
which cannot be connected with experiment, and so eliminated
all ideas of motion within the atom. We are unable to assign
to an electron a special position in space at a special instant of
time, so that, as far as our observations are concerned, an electron
orbit does not exist. In attempting to build up a new quantum
mechanics in which relations between observable magnitudes
* Heisenberg, Zeits. f. Physik, voi. 33, p. 879, 1925.
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