XVII. 4] THE NEW QUANTUM MECHANICS 237
E. It turns out that the only E values for which solutions exist
that are continuous, finite and single-valued throughout the
whole space are the following:
(1) E>o.
(2) E = — 27i 2 me*/h 2 n 2 {n = I, 2, 3, 4 . . .) . . 17 : 47
The first set of solutions corresponds to the hyperbolic orbits
in ordinary mechanics. It is indeed remarkable that in this
method of treatment these orbits appear quite spontaneously
from the fact that every positive value of E leads to finite
solutions. But what is even more remarkable is that the second
set corresponds exactly to Bohr’s stationary energy levels of
the circular or elliptic orbits. The selected values of E may be
named “ characteristic values ” (Eigenwerte), and the solutions
of the equation for ip belonging to them “ characteristic
functions.”
Schrodinger gives an interesting discussion of the question
why the equation for y should possess finite solutions only for
certain selected values of the constant E. Briefly it may be stated
that the first set of E values, E >> o, makes the square of the
phase-velocity positive throughout the space, the second set
makes this quantity negative. In the latter case “ there is in the
course of time a tendency to exaggerate infinitely all ‘ humps ’
of the function and even spontaneously to form humps out of
quite insignificant traces. Evidently a function which is subject
to such a revolutionary sort of equation, is continually exposed
to the very highest danger of increasing or decreasing beyond
all limit. At any rate it is no longer astonishing that special
conditions must be fulfilled to prevent such an occurrence.
The mathematical treatment shows that these conditions consist
exactly in E having one of the second set of characteristic
values.”
Another problem which may be solved by the methods of
undulatory mechanics is that of the harmonic oscillator. This
yields for the E levels the values (n + \)hv Q (where in this
case n may take the values 0, 1, 2, 3, 4 . . .) instead of nhv 0
as in the ordinary quantum theory. There is, then, this addi
tional term \hv 0 corresponding to what was suggested as being a
zero-point energy in some of the previous theories.
Another interesting problem solved by the new method is
that of a rotating body such as a molecule. If this body have
moment of inertia I, the E levels are given by n(n + i)h 2 /8jc 2 l.
In the ordinary theory instead of n(n + 1) we get n 2 .
In our actual observations we are interested only in differences
of level, and in this case the new formula amounts to the same
as replacing n 2 by (n + f) 2 , f° r { n + |) 2 — + 1) —