238 THE QUANTUM [xvn. 4
which is a constant and so disappears when we are considering
differences of levels. It may be recalled that so-called half
quantum numbers have been employed for some time in con
nection with band spectra.
Fues * * * § has worked out the band theory of diatomic molecules
in detail, taking into account the mutual influence of rotation
and oscillation and also the fact that the oscillation is not of the
simple harmonic type. The result is in exact agreement with
the ordinary treatment except that the quantum numbers be
come half-integral also in all correction terms.
A theory of the Stark effect based on Schrodinger’s ideas has
been presented by Epstein f who considers the radiation from a
hydrogen-like atom in an electric field. After a general mathe
matical exposition of the method, the positions of the components
are determined to terms of the second order in the electrical field.
The positions of the lines practically coincide with those obtained
in Epstein’s old theory which gave excellent agreement with
experiment. The main interest lies in the expressions for the
intensities, which are simple in their structure and agree with the
observed values better than the expressions derived by Kramers
from Bohr’s correspondence principle. A further point of interest
is that components which, in the old theory, had to be ruled out
by a special postulate, now drop out automatically. Schrodinger
himself has discussed the same problem and obtained similar
results.
A generalized operator calculus for dealing with the equations
of quantum dynamics has been developed by Carl Eckart J,
who claims that it leads to methods of solution much simpler
than those previously given. Born and Wiener § had previously
shown that the matrices were closely related to a special form of
operator, and that the operator calculus furnished a means of
calculating the matrices. Eckart shows that the results of
Schrodinger may be included in the matrix calculus of Born and
Jordan, thus giving an independent confirmation of Schrodinger’s
own presentation || (based on his wave-mechanics) of the mathe
matical equivalence of the two theories.
An interesting suggestion as to the physical meaning of the
wave-function ip has been made by Schrodinger. Let ip denote
a conjugate complex value. Then ipip is the square of the abso
lute value of the complex function ip and in the case of the
hydrogen atom is proportional to the charge of the electron,
* Fues, Ann. d. Physik, vol. 80, p. 367, 1926.
f Epstein, Phys. Rev., vol. 28, p. 659, 1926.
J Carl Eckart, Phys. Rev., vol. 28, p. 7x1, 1926.
§ Born and Wiener, Zeits. f. Physik, vol. 36, p. 174, 1926.
|| Schrodinger, Ann. d. Physik, vol. 79, p. 734, 1926.