2Ô0
THE QUANTUM
One first integral of the equations of motion expresses the fact
that the angular momentum is constant. That is
mr 2 p — constant = p (j)
corresponding to the second of Kepler’s laws. The equation of the
ellipse (eccentricity e, semi latus rectum l) may be written in this
form
me
ÿ = -pi f 1 + eC0S ^)
= |(l + ECOSp) .
(2)
an ordinary analytical expression for an ellipse in polar co-ordinates
p being taken as zero at perihelion.
The kinetic energy of the moving electron is
But
£
dr
Tp
T = ™(r* +
P dr
1 dp
p da
m dp
-esin p
and
v P p
rip — — =—o
T mr m
(i + £COS p)
Hence
The potential energy is
me*
T = ^2( T + 2£ COS p + £ 2 )
v — e — m&
r p
The total energy, H = T + V
me 4
and is constant as it should be.
2 (i + £COS p)
So we find
W = - H =
me-
2p 2
£ 2 )
(I - £ 2 )
(3)
(4)
(5)
(6)
(7)
(8)
(9)
The Quantum Relations.—We now have to introduce the restrictions
imposed by the quantum theory on the possible orbits. The expres
sions obtained for the energy show that the polar co-ordinates p, r are
canonical co-ordinates in the Hamiltonian sense, and may be regarded
as equivalent to q x , q 2 in the equations of restriction (p. 22).
We consider first the co-ordinate p, and “ quantize with respect
to the angular motion ” only, that is we impose the restriction
expressed by the equation
Ç2 IT p2ir
j p^dp = p J dp — 2np — n^h . . . (10)
According to quantum mechanics the angular momentum must be
an integral multiple of h/27i, which is the same condition as we