ATOMICITY IN ELECTRICITY
29
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cumstances in which they are exerted, definite for each body, we learn
to estimate the relative degree of force which resides in such bodies : and
when upon that knowledge comes the fact, that the electricity, which we
appear to be capable of loosening from its habitation for a while, and
conveying from place to place, whilst it retains its chemical force, can be
measured out, and being so measured is found to be as definite in its action
as any of those portions which, remaining associated with, the particles of
matter, give them their chemical relation ; we seem to have found the
link which connects the proportion of that we have evolved to the pro
portion of that belonging to the particles in their natural state.
869. The harmony which this theory of the definite evolution and
the equivalent definite action of electricity introduces into the associated
theories of definite proportions and electro-chemical affinity, is very great.
According to it, the equivalent weights of bodies are simply those quan
tities of them which contain equal quantities of electricity or have naturally
equal electric powers ; it being the electricity which determines the
equivalent number, because it determines the combining force. Or, if we
adopt the atomic theory or phraseology, then the atoms of bodies which
are equivalents to each other in their ordinary chemical action, have equal
quantities of electricity naturally associated with them. But I must con
fess I am jealous of the term atom ; for although it is very easy to talk
of atoms, it is very difficult to form a clear idea of their nature, especially
when compound bodies are under consideration.
Thus Faraday’s laws of electrolysis point clearly to an atomic
view of the constitution of electricity. This fact was emphasized
by Helmholtz in a celebrated lecture, commemorating Faraday’s
work, delivered in 1881. In 1874 Johnstone Stoney gave a
clear statement of the atomic theory of electricity, and in 1891
he suggested the term “ electron ” to designate the “ natural
unit of electricity,” which is that quantity of electricity which
must pass through a solution to liberate at one of the electrodes
one atom of hydrogen or one atom of any equivalent substance.
He even estimated the amount of the charge as 3 x io —11 absolute
electrostatic units of quantity. This is a somewhat smaller
value than that now accepted,
e = 4-774 x 10 10 E.S.U.*
Johnstone Stoney wrote : “A charge of this amount is
associated in the chemical atom with each bond. There may
accordingly be several such charges in one chemical atom, and
there appear to be at least two in each atom. These charges,
which it will be convenient to call ‘ electrons,’ cannot be
removed from the atom, but they become disguised when atoms
chemically unite. If an electron be lodged at the point P of
the molecule which undergoes the motion described in the last
chapter, the revolution of this charge will cause an electromagnetic
undulation in the surrounding ether.” f
* See Millikan, The Electron (University of Chicago Press, 1924).
f Johnstone Stoney, Sci. Trans. Roy. Dublin Soc., vol. 4, p. 563, 1891.