7 8
THE QUANTUM
[v. 4
Arrangement of Electrons in Rare Gases
(Main Smith and Stoner)
Atomic
number
K
Hi
L
2 u 2 21 2 22
M
3ll 321 322 332 3s3
N
4ll 421 422---
He
2
2
Ne
IO
2
224
A
18
2
224
2 2 4
Kr
36
2
224
22446
224
nie
ii
2 1 2 2
3l 32 33
4i 42
In the light of Stoner’s scheme of electron distribution,
Sommerfeld has recently given the following table to show the
classification of X-ray levels :
K
Li
Ln
Liu
M x
M„
M m
M IV
M v
K
L n
L 2 i
L 2 2
M u
M 21
M 22
M 32
M33
IS
2S
2pi
2^2
35
3Pi
3p2
3^2
3^3
2
2
2
4
2
2
4
4
6
Nx
N n
N ni
Niv
N v
Nvi
Nyii
N n
N„
n 22
N32
N33
N 43
N44
4 s
aPi
4P*
4^2
4^3
4/s
4 A
2
2
4
4
6
6
8
In the first line of the table is given the designation of the levels
according to Bohr and Coster ; in the second line the nomenclature
adopted by Sommerfeld in the new edition of his book, the double
suffixes corresponding to the k and j of Landé ; the third line
shows the correspondence throughout with the doublet character
of the alkalies, the subscript index giving the inner quantum
number j ; the last line gives the quantum weights of the respec
tive terms as 2j, which, according to Stoner, is equal to the
number of electrons in the completed X-ray sub-groups.
4. Complex Spectra and their Interpretation
A great advance in our knowledge of atomic states and spectral
terms has been brought about by the important researches of