VALUES OF LATENT HEAT AND SPECIFIC HEATS
79
(295) Latent Heat. r 2 = — T\ (vi — v 2 ) = 373 X 1657 X
go a l
27.2 X 3.1856 X 10 “ 5 = 535.5.
Example 4. Ice to Water at 0° by Melting
T 2 = 273 + 0 = 273.
v 2 = 1.00 volume of 1 gram of water at 0°.
v 3 = 1.09 volume of 1 gram of ice at 0°.
v 2 — v 3 = — 0.09.
— = 134.6 atmospheres.
a 1
(296) Latent Heat. r 3 =“~ • ^ (v 2 — v 3 ) = 273 X (— 0.09)
(-134.6) X 3.1856 X 10 _u X 760 = 80.066.
Example 5. Aqueous Vapor in Contact with Water at 100°.
dr 2
¿r=-°- 708
cp 2 = 1.0300
fdv 2 \
\dT)
P = 760 mm.
T = 373
001
dr 2
r 2
(318) cpi — cp 2 — Y ~ y
r 2
Vi - v 2
r/SDA
-1
L\377p
\dT)p]
535.5 535.5 tA
= - 0.708 - -373- + [4.931 -
0.001] = - 0.5504
Specific Heat. Cp\ = 1.0300 — 0.5490 = 0.4810.
Example 6. Water in Contact with Ice at 0°
'dv 2
dr 3
dT
= 0.6400
(H),-
(319) Cp 2
0.00006 = + 0.00011.
Cp 2 = 1.0000 water at 0°.
n . _dr 3 rs r 3 r /dv 2 \ _ fdv 3 \ -1
Cp3 ~ dT~ T + v 2 - v 3 LKdTjp \dTj P J
= 0.6400
v 2
80 80
273 + (-0.09)
[- 0.00006 -
0.00011]
= 0.6400 - 0.2930 + 0.1510 = 0.4980.
Specific Heat. Cp 3 = 1.0000 - 0.4980 = 0.5020.