found two types of eutectic structure, termed lamellar and anomalous.
Hollomon and Turnbull (3) investigated the solidification behavior
of supercooled Pb-Sn alloy droplets (30 to 50 in dia) as a function
of composition. Alloys were supercooled up to about 50°C and
showed structures with "cylindrical" dendrites and interdendritic
spaces occupied by "anomalous" eutectic.
Powell and Colligan (21) investigated the microstructure of super-
alv cooled hypereutectic Pb-67% Sn alloy. The final microstructure was
dendritic with a eutectic matrix. B.L. Jones and co-workers (9)
ching examined supercooled structure of Ag-Cu alloy. Their explanation of
the structures of supercooled Ag-Cu alloy ingots has shown that there
is coupled zone in this system. His "anomalous" structure consists
of a coupled and an uncoupled zone.
The structure of highly undercooled cobalt-tin alloy at hypoeutectic
a compositions was studied by Kattamis as a function of degree of
Ei supercooling. It was found that the cobalt rich o - phase was
dendritic for low undercooling, became cylindrical for intermediate
undercooling, and finally spherical for an undercooling higher than
about 170°C. In each case, a normal or divorced eutectic occupied
the space between the growth forms of the primary phase.
erent Y.V. Murty and T.Z. Kattamis (8) studied the structure of highly
supercooled cobalt-tin eutectic alloy and found that the amount of
les anomalous eutectic increased with supercooling and with cooling rate.
Both eutectics became finer with increasing supercooling and cooling
dify rate and both consisted of the same two phases. They suggested two
solidification models for explaining the formation of the observed
microstructures.
Scheil (22) distinguished between normal, anomalous and degenerate
eutectics. The definition of these groups is somewhat vague, and it
has been difficult to place some eutectics in the right group. Some
investigators even claim that all eutectics are probably normal. The
criterion of a normal eutectic, as defined by Scheil, is the
orientation relationship between the phases - no such orientation
ence, relationship is present in anomalous and degenerate eutectics. As
ic the eutectic structure depends upon both nucleation and growth, he
took the additional criterion that defines the group of eutectic -
ber the nucleation behavior. Only one of phases can nucleate the eutectic
crystallization, and in some systems no phase is effective.
A definition of the various groups of eutectics may be given as
follows:
21Q