1 
  
  
  
  
  
  
  
  
  
Chlorophyll. 
NH NH 
NIS c ENG 
: 1 Gn 
Phaeoporphyrin 4; ü | | I l i 
CuHsO,Nı (() H30———CH;—-CH,—-C0O0H Ba Der —CH; 
E 10-060 
| 1 
E a eo a 
NH 
Neo- ee rin 3 IN Ban a £ Ar 
(0, HsOs;N (II) 28 B= TER: Je | 
. H;C —CHs>s—CH:—COOH HO-0\ —CH; 
0C.H; an Stelle von OH = 
Phaeoporphyrin 3, (III) %o 
COOCH; 
i NH NH 
i NG BD un mr een ee a 
Phaeoporphyrin a; ! : | i | | i 
(uHs0;N; (IV) Hs0°—=—=—CH,—CH;—-C0O0OH BO, — CH; 
1700 
Vakte BE ehrt GOOCHEE Y 
a NH | 
NO NEE I A RI TE I 
Phylloerythrin i = Ta TE Tre — | N 
03 HsO:N, (V) B,C———10H,-CH,-000H H.O, „Lom 
, ee a Ben 2 
NH NH 
Sa : , 
Desoxo-phyllerythrin i ni Et en BA Eee [ Y e 
CsHnO:Ni VD H,C-—-CH,-CH,-000H HC, CH 
Ge 
NH NH 
NEN 
Chloroporphyrin & = m ——— reset m 
CaHaOsN, (VI) g,C——1 cH, CH, -000H CH, HO00C-.L 
er RE ER 
NH NH 
Ne N, NZ 
Chloroporphyrin e; i BR i | 
CuHuOsN: (vi) HC—=—=-CH,-CH,-C00H Hl Ar CH; 
© ‚co 
80% Nor 
Chloroporphyrin e; : a [ YY 
Os HnO4N 4 IX) mo! oH, 0H,-000H CH, H000-L_I cn, 
Rhodoporphyrin-y-carbon- \ RE a 
Te NH ei Ne 
säure N a | “ 
C3H30sN x 
PAuOeN, er JHr—-CH,;—C0O0OH COOH HO0C— u I_cH, 
NH NH 
Phaeoporphyrin a--trimethyl- II ES O NEL 
ester || 
(>, Hu0;N; (XI) H,C— — CH: —CH,—-CO0OCH; CO H;C00C— | cm, 
En ; ER COOCH, 7 
NH NH 
St EN N EN ee ee = G 7 BE 
Chloroporphyrin-e;-lacton- | | | 
_ dimethylester H;C— —CH,—CH,-COOH !-OH; 
(4HaOsN4 (XII) HO-0-00 
COOCH; Yv 
NH NH | 
Oxy-methylrhodoporphyrin- Nr N u an C EA <-| 
lacton | | | 
(3 Hs0,Ni (XIII) H;C- —CHs—CH:— COOH : —CH; 
H:;C—0—CO 
' Wichtigste 
1(1931): 
250 (1934). 
Verbindung vgl. 
486, 107 (1931).— Oxydationsprodukte: H. Fischer, 
H.Fischer, Süß: Liebigs Ann. 482, 225 (1930); 485, 
Heckmaier: Liebigs Ann. 508, 
= 
Hydrolyse ns 
  
203 
  
  
1 
  
Reduktion 
>> 
  
Jod in Eisessig 
BITERETESSRERRRERDIGETT 
InanReen 
TUHERERERETISEI FETTE