/
IONISATION, DIFFUSION, ROTATION
251
above Zi — 50. Of course, we give some attention to the changes required
if this assumed composition is considerably in error.
174. The fundamental formula for determining the degree of ionisation
of an element at given temperature and density is (47*1). Since a large
number of possible stages of ionisation and degrees of excitation may have
to be considered simultaneously the application of the formula may become
very complicated in practice. We give first a simplified discussion which
may, or may not, be accurate enough for actual computation, but will in
any case exhibit some of the more essential features of the problem.
The series of terms on the right-hand side of (47-1) corresponds to
atoms with successive degrees of excitation. We shall here suppose that
excitation is rare and that only the first term corresponding to unexcited
atoms need be considered. Further, we drop the weight factors q. Consider
the pth. ionisation and let ifj (= — y) be the energy required to remove the
pth electron. Then the ratio of the number of atoms with jp — 1 electrons
missing to the number with p electrons missing is by (47-1)
the logarithms being to the base 10.
For example, if T = 10 7 , p — *02, p, = 2,
conditions corresponding roughly to the centre of Capella, we have by
where the wave-length À corresponds to the energy ¡/r according to the
For brevity we often speak of an energy À, i.e. describe the quantity of
energy by the wave-length of the radiation having a quantum of this
amount.
(174*1),
where a is the number of free electrons per unit volume, so that
Neglecting as usual the small correction/, we have
(174*2)
x = 0*1, 0*5, 0*9,
0=ll-7i2T', 9*5 RT, 7*3 RT,
À = 1*22 Â, 1*51 Â, 1*96 Â,
for
and
quantum relation
ijj = he /À
(174*3).